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Home»Chemistry»Direct detection of SABRE-SHEATH hyperpolarization and spin-lattice relaxation of [1-13C]pyruvate
Chemistry

Direct detection of SABRE-SHEATH hyperpolarization and spin-lattice relaxation of [1-13C]pyruvate

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Direct detection of SABRE-SHEATH hyperpolarization and spin-lattice relaxation of [1-13C]pyruvate
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  • Hashemi, R., Bradley, W. & Lisanti, C.MRI: The Basics. The Basics Series (Lippincott Williams & Wilkins, 2010).

  • Grist, J. T. et al. Hyperpolarized 13C MRI: A novel approach for probing cerebral metabolism in health and neurological disease. J. Cereb. Blood Flow. Metab. 40, 1137–1147 (2020).


    Google Scholar
     

  • Marcone, M. F. et al. Diverse food-based applications of nuclear magnetic resonance (NMR) technology. Food Res. Int. 51, 729–747 (2013).


    Google Scholar
     

  • Patching, S. NMR-active nuclei for biological and biomedical applications. J. Diagn. Imaging Ther. 3, 7–48 (2016).


    Google Scholar
     

  • Abragam, A.The Principles of Nuclear Magnetism (Oxford University Press, 1983).

  • Aime, S., Castelli, D. D., Crich, S. G., Gianolio, E. & Terreno, E. Pushing the sensitivity envelope of lanthanide-based magnetic resonance imaging (MRI) contrast agents for molecular imaging applications. Acc. Chem. Res. 42, 822–831 (2009).


    Google Scholar
     

  • Lazarev, B. & Schubnikov, L. Magnetic moment of a proton. Phys. Zeitsch Der Sow. 11, 445–57 (1937).


    Google Scholar
     

  • Farra, T. Pulsed and Fourier transform NMR spectroscopy. Anal. Chem. 42, 109A–112A (1970).


    Google Scholar
     

  • Levitt, M. H.Spin dynamics: basics of nuclear magnetic resonance (Wiley, 2008).

  • Kanelis, V., Forman-Kay, J. D. & Kay, L. E. Multidimensional NMR methods for protein structure determination. IUBMB Life 52, 291–302 (2001).


    Google Scholar
     

  • Bydder, G., Hajnal, J. & Young, I. MRI: use of the inversion recovery pulse sequence. Clin. Radiol. 53, 159–176 (1998).


    Google Scholar
     

  • Freeman, R. & Hill, H. Fourier transform study of NMR spin–lattice relaxation by “progressive saturation”. J. Chem. Phys. 54, 3367–3377 (1971).


    Google Scholar
     

  • Chattergoon, N., Martínez-Santiesteban, F., Handler, W. B., Ardenkjær-Larsen, J. H. & Scholl, T. J. Field dependence of T1 for hyperpolarized [1-13C]pyruvate. Contrast Media Mol. Imaging 8, 57–62 (2013).


    Google Scholar
     

  • Eisenschmid, T. C. et al. Para hydrogen induced polarization in hydrogenation reactions. J. Am. Chem. Soc. 109, 8089–8091 (1987).


    Google Scholar
     

  • Abragam, A. & Goldman, M. Principles of dynamic nuclear polarisation. Rep. Prog. Phys. 41, 395 (1978).


    Google Scholar
     

  • Borghini, M., De Boer, W. & Morimoto, K. Nuclear dynamic polarization by resolved solid-state effect and thermal mixing with an electron spin-spin interaction reservoir. Phys. Lett. A 48, 244–246 (1974).


    Google Scholar
     

  • Adams, R. W. et al. Reversible interactions with para-hydrogen enhance NMR sensitivity by polarization transfer. Science 323, 1708–1711 (2009).


    Google Scholar
     

  • Truong, M. L. et al. 15N hyperpolarization by reversible exchange using SABRE-SHEATH. J. Phys. Chem. C. 119, 8786–8797 (2015).


    Google Scholar
     

  • Pravdivtsev, A. N. et al. Light-sabre hyperpolarizes 1-13C-pyruvate continuously without magnetic field cycling. J. Phys. Chem. C. 127, 6744–6753 (2023).


    Google Scholar
     

  • Tickner, B. J. et al. Optimisation of pyruvate hyperpolarisation using SABRE by tuning the active magnetisation transfer catalyst. Catal. Sci. Technol. 10, 1343–1355 (2020).


    Google Scholar
     

  • TomHon, P. et al. Temperature cycling enables efficient 13C SABRE-SHEATH hyperpolarization and imaging of [1-13C]-pyruvate. J. Am. Chem. Soc. 144, 282–287 (2021).


    Google Scholar
     

  • Theis, T. et al. Microtesla SABRE enables 10% nitrogen-15 nuclear spin polarization. J. Am. Chem. Soc. 137, 1404–1407 (2015).


    Google Scholar
     

  • Fekete, M., Ahwal, F. & Duckett, S. B. Remarkable levels of 15N polarization delivered through SABRE into unlabeled pyridine, pyrazine, or metronidazole enable single scan NMR quantification at the mM level. J. Phys. Chem. B 124, 4573–4580 (2020).


    Google Scholar
     

  • Iali, W. et al. Hyperpolarising pyruvate through signal amplification by reversible exchange (SABRE). Angew. Chem. Int. Ed. 58, 10271–10275 (2019).


    Google Scholar
     

  • Cowley, M. J. et al. Iridium N-heterocyclic carbene complexes as efficient catalysts for magnetization transfer from para-hydrogen. J. Am. Chem. Soc. 133, 6134–6137 (2011).


    Google Scholar
     

  • Assaf, C. D. et al. J coupling constants of J. Phys. Chem. Lett. 15, 1195–1203 (2024).

  • Pravdivtsev, A. N., Yurkovskaya, A. V., Vieth, H.-M., Ivanov, K. L. & Kaptein, R. Level anti-crossings are a key factor for understanding para-hydrogen-induced hyperpolarization in SABRE experiments. ChemPhysChem 14, 3327–3331 (2013).


    Google Scholar
     

  • Myers, W. et al. Calculated signal-to-noise ratio of MRI detected with SQUIDs and Faraday detectors in fields from 10 μT to 1.5 T. J. Magn. Reson. 186, 182–192 (2007).


    Google Scholar
     

  • Myers, J. Z., Buckenmaier, K., Pravdivtsev, A. N., Plaumann, M. & Körber, R. Characterization of nuclear magnetism at ultralow and zero field using SQUIDs. IEEE Trans. Appl. Supercond. 35, 1–5 (2025).

  • Cohen-Tannoudji, C., DuPont-Roc, J., Haroche, S. & Laloë, F. Detection of the static magnetic field produced by the oriented nuclei of optically pumped 3He gas. Phys. Rev. Lett. 22, 758–760 (1969).


    Google Scholar
     

  • Eills, J., Mitchell, M. W., Rius, I. M. & Tayler, M. C. D. Live magnetic observation of parahydrogen hyperpolarization dynamics. Proc. Natl. Acad. Sci. 121, e2410209121 (2024).

  • Mouloudakis, K. et al. Real-time polarimetry of hyperpolarized 13C nuclear spins using an atomic magnetometer. J. Phys. Chem. Lett. 14, 1192–1197 (2023).


    Google Scholar
     

  • Buckenmaier, K. et al. Multiple quantum coherences hyperpolarized at ultra-low fields. ChemPhysChem 20, 2823–2829 (2019).


    Google Scholar
     

  • Peters, J. P., Assaf, C. D., Hövener, J.-B. & Pravdivtsev, A. N. Compact magnetic field cycling system with the range from nT to 9.4 T exemplified with 13C relaxation dispersion and SABRE-SHEATH hyperpolarization (2025).

  • Buckenmaier, K. et al. Indirect zero-field nuclear magnetic resonance spectroscopy. Anal. Chem. 97, 17336–17344 (2025).

  • Myers, J. Z. et al. Zero to ultralow magnetic field NMR of [1-13C] pyruvate and [2-13C] pyruvate enabled by SQUID sensors and hyperpolarization. Phys. Rev. B 109, 184443 (2024).


    Google Scholar
     

  • Adams, R. W., Duckett, S. B., Green, R. A., Williamson, D. C. & Green, G. G. R. A theoretical basis for spontaneous polarization transfer in non-hydrogenative parahydrogen-induced polarization. J. Chem. Phys. 131, 194505 (2009).


    Google Scholar
     

  • Hövener, J.-B., Knecht, S., Schwaderlapp, N., Hennig, J. & von Elverfeldt, D. Continuous re-hyperpolarization of nuclear spins using parahydrogen: Theory and experiment. ChemPhysChem 15, 2451–2457 (2014).


    Google Scholar
     

  • Natterer, J. & Bargon, J. Parahydrogen induced polarization. Prog. Nucl. Magn. Reson. Spectrosc. 31, 293–315 (1997).


    Google Scholar
     

  • Pravdivtsev, A. N., Yurkovskaya, A. V., Ivanov, K. L. & Vieth, H.-M. Importance of polarization transfer in reaction products for interpreting and analyzing CIDNP at low magnetic fields. J. Magn. Reson. 254, 35–47 (2015).


    Google Scholar
     

  • Pravdivtsev, A. N. & Hövener, J.-B. Coherent polarization transfer in chemically exchanging systems. Phys. Chem. Chem. Phys. 22, 8963–8972 (2020).


    Google Scholar
     

  • Lindale, J. R. et al. Multi-axis fields boost SABRE hyperpolarization. Proc. Natl. Acad. Sci. 121 (2024).

  • Pravdivtsev, A. N. et al. Coherent evolution of signal amplification by reversible exchange in two alternating fields (Alt-SABRE). ChemPhysChem 22, 2381–2386 (2021).


    Google Scholar
     

  • Lindale, J. R. et al. Unveiling coherently driven hyperpolarization dynamics in signal amplification by reversible exchange. Nat. Commun. 10, 395 (2019).


    Google Scholar
     

  • Eriksson, S. L., Lindale, J. R., Li, X. & Warren, W. S. Improving SABRE hyperpolarization with highly nonintuitive pulse sequences: Moving beyond avoided crossings to describe dynamics. Sci. Adv. 8, eabl3708 (2022).

  • Brown, E. et al. Photo-ejected ligands hyperpolarized by parahydrogen in reversible exchange. Chem. Commun. 61, 4674–4677 (2025).

  • Vázquez-Serrano, L. D., Owens, B. T. & Buriak, J. M. Catalytic olefin hydrogenation using N-heterocyclic carbene–phosphine complexes of iridium. Chem. Commun. 21, 2518–2519 (2002).

  • Voigt, J., Knappe-Grüneberg, S., Schnabel, A., Körber, R. & Burghoff, M. Measures to reduce low residual field and field gradient inside a magnetically shielded room by a factor of more than 10. Metrol. Meas. Syst. 21, 239–248 (2013).


    Google Scholar
     

  • Storm, J.-H., Hömmen, P., Drung, D. & Körber, R. An ultra-sensitive and wideband magnetometer based on a superconducting quantum interference device. Appl. Phys. Lett. 110, 072603 (2017).


    Google Scholar
     

  • Hömmen, P.Realization of current density imaging using ultra-low-field MRI. Ph.D. thesis, Technische Universität Ilmenau (2021). Dissertation, Technische Universität Ilmenau, (2021).



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    113Cpyruvate Chemistry/Food Science Detection direct General hyperpolarization relaxation SABRESHEATH Solution-state NMR spinlattice
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