Should you require a model for an Oxford don in a play or novel, look no farther than Andrew Briggs. The emeritus professor of nanomaterials speaks with a southern-English accent as crisp as shortbread, exhibits manners to which etiquette influencer William Hanson could aspire, and can discourse about anything from Bantu to biblical Hebrew. I joined Andrew for lunch at St. Anne’s College, Oxford, this month.1 Over vegetable frittata, he asked me what unifying principle distinguishes quantum from classical thermodynamics.
I’d approached quantum thermodynamics from nearly every angle I could think of. I’d marched through the thickets of derivations and plots; I’d journeyed from subfield to subfield; I’d gazed down upon the discipline as upon a landscape from a hot-air balloon. I’d even prepared a list of thermodynamic tasks enhanced by quantum phenomena: we can charge certain batteries at greater powers if we entangle them than if we don’t, entanglement can raise the amount of heat pumped out of a system by a refrigerator, etc. But Andrew’s question flummoxed me.
I bungled the answer. I toted out the aforementioned list, but it contained examples, not a unifying principle. The next day, I was sitting in an office borrowed from experimentalist Natalia Ares in New College, a Gothic confection founded during the late 1300s (as one should expect of a British college called “New”). Admiring the view of ancient stone walls, I realized how I should have responded the previous day.
My answer begins with a blog post written in response to a quantum-thermodynamics question from a don at another venerable university: Yoram Alhassid. He asked, “What distinguishes quantum thermodynamics to quantum statistical mechanics?” You can read the full response here. Takeaways include thermodynamics’s operational flavor. When using an operational theory, we imagine agents who perform tasks, using given resources. For example, a thermodynamic agent may power a steamboat, given a hot gas and a cold gas. We calculate how effectively the agents can perform those tasks. For example, we compute heat engines’ efficiencies. If a thermodynamic agent can access quantum resources, I’ll call them “quantum thermodynamic.” If the agent can access only everyday resources, I’ll call them “classical thermodynamic.”
A quantum thermodynamic agent may access more resources than a classical thermodynamic agent can. The latter can leverage work (well-organized energy), free energy (the capacity to perform work), information, and more. A quantum agent may access not only those resources, but also entanglement (strong correlations between quantum particles), coherence (wavelike properties of quantum systems), squeezing (the ability to toy with quantum uncertainty as quantified by Heisenberg and others), and more. The quantum-thermodynamic agent may apply these resources as described in the list I rattled off at Andrew.
Yet quantum phenomena can impede a quantum agent in certain scenarios, despite assisting the agent in others. For example, coherence can reduce a quantum engine’s power. So can noncommutation. Everyday numbers commute under multiplication: 11 times 12 equals 12 times 11. Yet quantum physics features numbers that don’t commute so. This noncommutation underlies quantum uncertainty, quantum error correction, and much quantum thermodynamics blogged about ad nauseam on Quantum Frontiers. A quantum engine’s dynamics may involve noncommutation (technically, the Hamiltonian may contain terms that fail to commute with each other). This noncommutation—a fairly quantum phenomenon—can impede the engine similarly to friction. Furthermore, some quantum thermodynamic agents must fight decoherence, the leaking of quantum information from a quantum system into its environment. Decoherence needn’t worry any classical thermodynamic agent.
In short, quantum thermodynamic agents can benefit from more resources than classical thermodynamic agents can, but the quantum agents also face more threats. This principle might not encapsulate how all of quantum thermodynamics differs from its classical counterpart, but I think the principle summarizes much of the distinction. And at least I can posit such a principle. I didn’t have enough experience when I first authored a blog post about Oxford, in 2013. People say that Oxford never changes, but this quantum thermodynamic agent does.
In the University of Oxford Natural History Museum in 2013, 2017, and 2025. I’ve published nearly 150 Quantum Frontiers posts since taking the first photo!
1Oxford consists of colleges similarly to how neighborhoods form a suburb. Residents of multiple neighborhoods may work in the same dental office. Analogously, faculty from multiple colleges may work, and undergraduates from multiple colleges may major, in the same department.
